کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
171690 | 458471 | 2006 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The composition, charge and architecture of hydronium ions as observed in the crystalline state
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The structures of hydronium ions present in single crystals have, by and large, been thought as being relatively simple and characterized by the classical formulae H3O+, H5O2+, H7O3+ and H9O4+. All of them are thought to be quasi-planar, acyclic entities of charge +1, exclusively. In this review, we show that such is not the case in view of the fact that there exist documented examples of cyclic hydronium ions, that their charge can be larger than +1 and that they exist in aggregates containing more than four oxygens. Moreover, it is documented that hydronium ions exist in the form of geometrical isomers or conformers. To cite this article: I. Bernal, C. R. Chimie 9 (2006).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Comptes Rendus Chimie - Volume 9, Issues 11–12, November–December 2006, Pages 1454–1466
Journal: Comptes Rendus Chimie - Volume 9, Issues 11–12, November–December 2006, Pages 1454–1466
نویسندگان
Ivan Bernal,