کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
175452 | 458910 | 2016 | 8 صفحه PDF | دانلود رایگان |
• Derivative of oxygafluorene and di-tert-butyl carbazole was synthesized.
• The solid sample showed triplet energy of 2.81 eV.
• The hole mobility reached 10−2 cm2V−1s−1 at high electric fields.
• Blue devices showed external quantum efficiency of 16.5%.
Derivative of oxygafluorene and di-tert-butyl carbazole was synthesized as the host material for high-efficiency blue phosphorescent organic light-emitting diodes. It exhibited moderate thermal stability with 5% weight loss temperature of 337 °C and glass-forming ability with the glass-transition temperature of 65 °C. The solid-state ionization potential of di-tert-butyl carbazolyl-substituted oxygafluorene was found to be 5.54 eV as established by electron photoemission spectrometry. It showed low-dispersity hole transport with time-of-flight hole mobilities of 10−2 cm2 V−1 s−1 observed at high electric fields. Blue devices based on the synthesized compound showed high external quantum efficiency up to 16.5% and low efficiency roll-off.
Journal: Dyes and Pigments - Volume 130, July 2016, Pages 298–305