Influence of CeO2 on structural properties of glasses by using ultrasonic technique: Comparison between the local sand and SiO2

Comparison between the local sand and SiO2 with different compositions of CeO2 on the structural properties of glasses was carried out by using ultrasonic technique. The ultrasonic velocities were measured by the pulse echo technique with a frequency of 4 MHz and at room temperature. From these obtained velocities and densities, various elastic moduli, micro-hardness and Poisson’s ratio were calculated. The interesting point of the bulk modulus (SiO2 glass system) decreases at x = 1.25 mol.% initially before it turns to increase between x = 3.75 and x = 5.00 mol.%. While the bulk modulus of the local sand glass system is near constant. FTIR spectra were used to study the structural properties of the prepared glass system. The results supported our discussion of the formation of non-bridging oxygens (NBO) and bridging oxygens (BO).

► Comparison the structural properties of glass between local sand and SiO2.
► A broken structure due to the addition of CeO2 can be checked by ultrasonic.
► Sample of LGS group more suitable the SGS group in term of change in cross-linkage.