کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
175941 458928 2015 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influence of bulky pyrrolyl substitent on the physicochemical properties of porphyrazines
ترجمه فارسی عنوان
تأثیر ضریب پیکرولیل بزرگ بر خواص فیزیکوشیمیایی پورفیرازین
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


• Syntheses of porphyrazines possessing 2,5–diphenylpyrrol-1-yl groups are reported.
• Physicochemical properties and solid-state structure of porphyrazines are discussed.
• Spin state of iron ion inside the core of iron(II) porphyrazine was investigated.

The synthesis and characterization of porphyrazines possessing 2,5–diphenylpyrrol-1-yl and dimethylamino peripheral groups and their precursors are shown. Bulky pyrrolyl substituents influenced the physicochemical properties and solid-state structure of novel porphyrazines and did not hamper the formation of the porphyrazine associates in solution and solid-state. Occurrence of centrosymmetric dimers in single crystal X-ray structure of magnesium(II) porphyrazine with Mg⋯Mg distance of ca. 11.2 Å, impacted by interdigitation of the phenyl substituents, was noticed. In addition, an iron(II) porphyrazine derivative was investigated. The importance of Mössbauer spectroscopy in the assessment of valence and spin state of the iron ion inside the core of the iron(II) porphyrazine is shown.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 112, January 2015, Pages 138–144
نویسندگان
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