کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
176064 | 458931 | 2014 | 6 صفحه PDF | دانلود رایگان |
• The first N-acylated isoindigo monomer was reported.
• Polymers based on the new monomer showed broad absorptions and deep LUMO levels.
• The new polymers were studied as semiconductors in OTFT devices.
Donor/acceptor polymers with N-acylated isoindigo as acceptor units have been synthesized. The thermal, optical, electrochemical, and charge-transport properties of the polymers have been investigated. The new polymers show broad absorption from 450 to 900 nm. Due to the strong electron accepting characteristic of N-acylated isoindigo, the new polymers exhibit narrow optical band gaps and deep LUMO energy levels compared with the polymers based on N-alkylated isoindigo. The new polymers show n-type transport behavior and balanced ambipolar transport behavior in organic thin film transistors (OTFT) device.
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Journal: Dyes and Pigments - Volume 109, October 2014, Pages 200–205