کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
176562 | 458947 | 2012 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and photochromic properties of spiro[naphthopyran-7′H-benzocyclohepta-5′,8′-dienes]
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
A series of spironaphthopyrans has been synthesised by the acid-catalysed condensation between either a substituted 1-naphthol or 2-naphthol and the propargylic alcohol derived from the addition of lithium trimethylsilylacetylide to a 7H-benzocycloheptan-7-one with subsequent in situ silyl group removal. The photochromism of the novel spironaphthopyrans was characterised by a bathochromically shifted λmax coupled with a relatively quick initial fade of the photogenerated species relative to the comparable diphenyl substituted model compounds. After initial fading a relatively intense residual colour persisted for the spironaphthopyrans.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 95, Issue 1, October 2012, Pages 62–68
Journal: Dyes and Pigments - Volume 95, Issue 1, October 2012, Pages 62–68
نویسندگان
Daniel L. Crossley, Christopher D. Gabbutt, B. Mark Heron, Paul Kay, Martin Mogstad,