کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
176623 458950 2013 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and photophysical studies of a chlorin sterically designed to prevent self-aggregation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Synthesis and photophysical studies of a chlorin sterically designed to prevent self-aggregation
چکیده انگلیسی

Synthesis and photophysical evaluations of a new non-aggregating chlorin derivative are described. A β-octa(carboxyethyl)porphyrin 3 was synthesized in 2 steps starting from pyrrole-3,4-dicarboxylic acid diethyl ester (2). The new chlorin derivative 6 was obtained through a 1,3-dipolar cycloaddition using benzyl azomethine ylide. Chlorin 6 presents a molecular scaffold in an “L” shape avoiding aggregation in solutions at 1–27 mM. Photophysical properties were measured, and indicate that this new compound can be considered a useful candidate for PDT studies.

Figure optionsDownload as PowerPoint slideHighlights
► Synthesis of a new non-aggregating chlorin derivative is described.
► A 1,3-dipolar cycloaddition was used as the key step.
► This new chlorin has proven to be a good candidate for PDT studies.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 98, Issue 1, July 2013, Pages 153–159
نویسندگان
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