کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
176644 | 458951 | 2012 | 9 صفحه PDF | دانلود رایگان |
New bi-anchoring donor-π-acceptor (D-π-A) metal-free organic dyes based on diphenylamine, carbazole as donor, cyano vinyl biphenyl as a π-linker and cyanoacrylic acid, rhodanine-3-acetic acid as acceptor/anchor are synthesized, characterized and used for the dye-sensitized solar cell (DSSC) applications. Among the fabricated DSSCs, device based on the carbazole as donor, cyano vinyl biphenyl as a π-linker and cyanoacrylic acid as acceptor exhibits a high power conversion efficiency of 2.37% with a short-circuit current density of 5.18 mAcm−2, an open-circuit photo voltage of 0.766 V and a fill factor of 50.8% under AM1.5 illumination (85 mWcm−2) compared to other devices.
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► Synthesis of new bi-anchoring donor-π-acceptor (D-π-A) metal-free organic dyes.
► Studies of properties such as electrochemical, photophysical and theoretical by appropriate methods.
► Fabricated photovoltaic device based on carbazole as donor and cyanoacrylic acid as acceptor shows good efficiency.
Journal: Dyes and Pigments - Volume 94, Issue 3, September 2012, Pages 503–511