کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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176957 | 458961 | 2012 | 7 صفحه PDF | دانلود رایگان |

1-Aminoperylene bisimides (1a–1c) were synthesized under mild condition in high yields, and were characterized by FT-IR, 1H NMR, UV–Vis, HRMS spectra, cyclic voltammetry, differential scanning calorimetry, and thermogravimetric analyses. These compounds are stable up to 310 °C according to thermogravimetric analyses. They undergo two quasi-reversible one-electron oxidations and two quasi-reversible one-electron reductions in dichloromethane at modest potentials. Their spectroscopic properties in various conditions and complementary density functional theory (DFT) calculations are reported.
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► 1-Aminoperylene bisimides were synthesized under mild condition in high yields.
► These molecules undergo an exicted-state intramolecular electron transfer reaction, resulting in a unique charge transfer emission.
► They display good thermal stability as well as good optical stability and reversible redox properties.
Journal: Dyes and Pigments - Volume 92, Issue 1, January 2012, Pages 517–523