کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
177234 | 458971 | 2010 | 6 صفحه PDF | دانلود رایگان |

A tetranitrile monomer was synthesized by nucleophilic aromatic substitution of N,N′-(2,2′-(propane-1,3-diylbis(sulfanediyl))bis(ethane-2,1-diyl))bis(4-methylbenzenesulfonamide) onto 4-nitrophthalonitrile. A metal-free phthalocyanine polymer was prepared by the reaction of the tetranitrile monomer under N2 in the presence of 2-(dimethylamino)ethanol at 145 °C for 24 h. Zinc(II), copper(II), cobalt(II), nickel(II), lead(II), phthalocyanine polymers were prepared by reaction of the tetranitrile with the chlorides of zinc (II), copper (II), cobalt (II), nickel (II), lead (II), employing microwave irradiation in the presence 2-(dimethylamino)ethanol at 175 °C, 350 W for 10 min. The thermal stabilities of the phthalocyanine compounds were determined by thermogravimetric analysis. The new compounds were characterized by a combination of IR, 1H NMR, 13C NMR, UV–vis, elemental analysis and MS spectral data.
Journal: Dyes and Pigments - Volume 85, Issue 3, May 2010, Pages 177–182