کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
177402 458982 2011 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, application and investigation of structure–thermal stability relationships of thermally stable water-soluble azo naphthalene dyes for LCD red color filters
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Synthesis, application and investigation of structure–thermal stability relationships of thermally stable water-soluble azo naphthalene dyes for LCD red color filters
چکیده انگلیسی

A series of structurally isomeric water-soluble azo naphthalene dyes were synthesized, and their thermal properties were examined by thermogravimetric analysis and differential scanning calorimetry. Dye-based color filters were also fabricated using the synthesized dyes. Transmittance (98.9%) at 650 nm and a wide color gamut (62.8%) were achieved using one of the color filters. All the prepared dyes had a degradation temperature above 280 °C, which varied with the dye structure. The degradation temperatures of the dyes were presumed to be related to the intra- and inter-molecular interactions of the structural isomers. From quantum mechanics calculations, their intra-molecular interactions were similar. However, the degradation temperatures generally increased in proportion to their density. According to the molecular mechanics calculations, the different structures induced changes in electrostatic attraction, steric hindrance and linearity of the dyes, which in turn caused changes in their molecular packing geometry, density and degradation temperature.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 89, Issue 1, April 2011, Pages 1–8
نویسندگان
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