کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
177641 458992 2009 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Chromogenic anionic chemosensors based on protonated merocyanine solvatochromic dyes: Influence of the medium on the quantitative and naked-eye selective detection of anionic species
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Chromogenic anionic chemosensors based on protonated merocyanine solvatochromic dyes: Influence of the medium on the quantitative and naked-eye selective detection of anionic species
چکیده انگلیسی

Three merocyanine solvatochromic dyes, Brooker's merocyanine, Reichardt's dye and 4-(2,4,6-triphenylpyridinium-1-yl)phenolate were solubilized in acetonitrile. Although solutions of each of the compounds are colored, the color disappears after protonation. Addition of various anions to solutions of the protonated dyes revealed that only CN−, F−, and H2PO4− led to the reappearance of the original color of protonated Reichardt's dye, and only CN− and F− ions caused the original color of the solutions containing the other two protonated dyes to reappear. Addition of small amounts of water to solutions containing the protonated compounds made them useful only for detecting CN− among all the other anions. A model was used to explain the experimental results, which considers proton transfer from the protonated dye to the anion through three dye:anion stoichiometries, namely 1:1, 1:2, and 1:3.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 82, Issue 2, August 2009, Pages 187–195
نویسندگان
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