کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
177760 | 459000 | 2009 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: The synthesis, two-photon absorption and blue upconversion fluorescence of novel, nitrogen-containing heterocyclic chromophores The synthesis, two-photon absorption and blue upconversion fluorescence of novel, nitrogen-containing heterocyclic chromophores](/preview/png/177760.png)
Novel, nitrogen-containing heterocyclic chromophores based on either 1,2,4-triazine or an imidazole core were synthesized using a three-component, one-pot reaction under microwave irradiation. Structures were verified by 1H NMR, IR, MS and elemental analyses while crystal structure was determined using X-ray diffraction. The two-photon absorption and two-photon upconverted blue fluorescent emission characteristics were investigated experimentally; preliminary structure–photophysical property relationships were established. Chromophores that contained the imidazole moiety displayed more potent two-photon absorption than compounds based upon 1,2,4-triazine and also exhibited a strong two-photon upconverted blue fluorescent emission peak at around 443–476 nm. Significant enhancement of the two-photon absorption cross-section was achieved by fusing a benzoxazole moiety onto the phenanthro[9,10-d]imidazole ring.
Journal: Dyes and Pigments - Volume 81, Issue 1, April 2009, Pages 10–17