کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
177817 459002 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A novel, one-pot method for the synthesis of dimeric and monomeric phthalocyanine silicon complexes from free-base phthalocyanines
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
A novel, one-pot method for the synthesis of dimeric and monomeric phthalocyanine silicon complexes from free-base phthalocyanines
چکیده انگلیسی

A novel method for the synthesis of dimeric and monomeric phthalocyanine silicon complexes using a one-pot method, from tetra-substituted free-base phthalocyanines in the presence of HSiCl3 at room temperature, is described. Silation was carried out using different bases and the reaction time and the order of addition of the chemicals were varied. It was found that by changing the reaction conditions, it was possible to synthesize either monomers or dimeric complexes with direct Si–Si bonds, selectively.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 83, Issue 3, December 2009, Pages 317–323
نویسندگان
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