کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
177825 | 459002 | 2009 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and properties of phthalocyanine zinc(II) complexes replaced with oxygen and sulfur linked adamantane moieties
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Novel, zinc (II) phthalocyanines substituted with 2-adamantanol and 1-adamantanethiol moieties were prepared from the corresponding phthalonitriles employing commercially available 3- and 4-nitrophthalonitrile as the starting material. The Q-band of tetra-α-substituted phthalocyanines occurred at longer wavelengths than those of the corresponding, tetra-β-substituted phthalocyanines. Substituents at the β position increased ΦF values; all phthalocyanines studied displayed excellent singlet oxygen generations ability, with α-substituted dyes showing higher ΦΔ values than their β-isomers. The dyes exhibited good photo-stability, with α-substituted phthalocyanines proving to be of higher stability than the corresponding β-isomers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 83, Issue 3, December 2009, Pages 375–380
Journal: Dyes and Pigments - Volume 83, Issue 3, December 2009, Pages 375–380
نویسندگان
María C. García Vior, Lelia E. Dicelio, Josefina Awruch,