کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
177825 459002 2009 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and properties of phthalocyanine zinc(II) complexes replaced with oxygen and sulfur linked adamantane moieties
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Synthesis and properties of phthalocyanine zinc(II) complexes replaced with oxygen and sulfur linked adamantane moieties
چکیده انگلیسی

Novel, zinc (II) phthalocyanines substituted with 2-adamantanol and 1-adamantanethiol moieties were prepared from the corresponding phthalonitriles employing commercially available 3- and 4-nitrophthalonitrile as the starting material. The Q-band of tetra-α-substituted phthalocyanines occurred at longer wavelengths than those of the corresponding, tetra-β-substituted phthalocyanines. Substituents at the β position increased ΦF values; all phthalocyanines studied displayed excellent singlet oxygen generations ability, with α-substituted dyes showing higher ΦΔ values than their β-isomers. The dyes exhibited good photo-stability, with α-substituted phthalocyanines proving to be of higher stability than the corresponding β-isomers.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 83, Issue 3, December 2009, Pages 375–380
نویسندگان
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