|کد مقاله||کد نشریه||سال انتشار||مقاله انگلیسی||ترجمه فارسی||نسخه تمام متن|
|178730||459316||2016||4 صفحه PDF||سفارش دهید||دانلود رایگان|
• Effect of water on an ionic liquid/Au electrode interface was investigated by SEIRAS.
• Potential-dependent interfacial structure was revealed at the molecular scale.
• Water condensation on a positively charged electrode was observed for the first time.
• Strong anion–water interaction plays a key role in the water condensation.
Surface-enhanced infrared absorption spectroscopy (SEIRAS) at the interface between humid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide ([BMIM][TFSA]) and an Au electrode reveals that water molecules strongly interact with the anion and are condensed at the interface at high potentials where the anion is the major adsorbate.
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Journal: Electrochemistry Communications - Volume 65, April 2016, Pages 14–17