کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
178789 | 459319 | 2015 | 4 صفحه PDF | دانلود رایگان |
• The combination of VC + LiDFP improves the rate capability of graphite.
• VC reinforces the mechanical property of the LiDFP-derived SEI.
• The nature of the SEI is a key parameter affecting the kinetics of graphite.
Lithium difluorophosphate (LiDFP) as a reducible additive is employed to overcome the unsatisfactory rate capability and cycling instability of highly pressed graphite electrodes with high mass loading (8.1 mg/cm2) with a vinylene carbonate (VC)-derived surface film that hampers the charge transport at the graphite–electrolyte interface at high rates. Our investigation reveals that LiDFP modifies the surface chemistry induced by VC and makes a more ionically conductive surface film on graphite, ensuring good rate capability.
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Journal: Electrochemistry Communications - Volume 61, December 2015, Pages 121–124