کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
178836 | 459322 | 2015 | 4 صفحه PDF | دانلود رایگان |
• LLZTO solid electrolyte can be short-circuited by lithium dendrites.
• The period before short-circuit positively correlates to the relative density.
• Lithium dendrites are observed directly inside short-circuited LLZTO electrolyte.
• Lithium dendrites can grow through grain boundaries and interconnected pores.
This work investigated the resistance of Al-contained Li6.75La3Zr1.75Ta0.25O12 (LLZTO) sintered pellets to lithium dendrites. The short-circuiting period for Li/LLZTO/Li cells under a high applied direct current showed positive correlation to the variation in the relative densities of the LLZTO pellets sintered at different temperatures. Lithium dendrites were observed directly inside short-circuited LLZTO electrolytes. Our observations demonstrate that lithium dendrites can grow through grain boundaries and interconnected pores in the ceramic electrolytes.
Journal: Electrochemistry Communications - Volume 57, August 2015, Pages 27–30