کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
179131 | 459337 | 2014 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Selective monocarboxylation of olefins at 12CaO·7Al2O3 electride cathode
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
• Highly efficient and selective carboxylation of olefins to form monocarboxylic products was successfully achieved using a novel cathode material named C12A7 electride under carbon dioxide atmosphere in a divided cell without sacrificial anode.
Metallic oxide conductor 12CaO·7Al2O3 (C12A7) electride with high affinity to CO2, a new candidate for the cathode material in electrochemistry, is used for the selective monocarboxylaiton of various olefins. The galvanostatic electrolysis was performed under carbon dioxide atmosphere without sacrificial anode in a divided cell. The monocarboxylic products were obtained in moderate to high yield (58−91%), which were significantly higher than those at Pt (9−83%) and glassy carbon (32−72%) cathode.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 44, July 2014, Pages 45–48
Journal: Electrochemistry Communications - Volume 44, July 2014, Pages 45–48
نویسندگان
Jiang Li, Shinsuke Inagi, Toshio Fuchigami, Hideo Hosono, Setsuro Ito,