Nitroxyl radical self-assembled monolayers: Generalized lateral interactions model used with binary electrolyte mixture

The electrochemical behavior of redox centers on self-assembled monolayer (SAM) was interpreted through the generalized lateral interactions model when the electrolyte medium is composed of miscible solvents.Electrochemical behaviors of nitroxyl radical SAMs provide evidence of a linear dependence of interaction parameters with the ratio of the two solvents.

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► Generalized lateral interactions model can be used with binary electrolyte mixtures.
► The dependence of interaction parameters on the ratio of two solvents is linear.