کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
179490 459352 2013 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
3D analysis of a LiCoO2–Li(Ni1/3Mn1/3Co1/3)O2 Li-ion battery positive electrode using x-ray nano-tomography
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
3D analysis of a LiCoO2–Li(Ni1/3Mn1/3Co1/3)O2 Li-ion battery positive electrode using x-ray nano-tomography
چکیده انگلیسی

A full-field high-resolution x-ray nano-tomography technique, transmission x-ray microscopy (TXM), was used to reveal the 3D morphology of the lithium ion battery composite positive electrode: LiCoO2 (LCO)–Li(Ni1/3Mn1/3Co1/3)O2 (NMC). The TXM method allowed the unambiguous chemical identification of oxide particles by tuning the x-ray energy relative to the transition-metal absorption edges. The NMC particles have a much rougher surface compared to the LCO particles. Cracks due to processing exist in both LCO and NMC particles but the NMC particles exhibit more severe cracking and also tend to have internal pores in addition to radial cracks. Further, the carbon-based phases including the binder and the conductive carbon were identified using Zernike phase contrast imaging.


► First 3D x-ray nano-tomography of electrode with multiple active phases
► Unambiguous chemical identification of oxide particles
► Different cracks in LiCoO2 and Li(Ni1/3Mn1/3Co1/3)O2
► Quantitative curvature analysis shows small radius in Li(Ni1/3Mn1/3Co1/3)O2.
► Observation of continuous and uniform carbon-based phase distribution

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 28, March 2013, Pages 127–130
نویسندگان
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