کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
179535 | 459355 | 2013 | 4 صفحه PDF | دانلود رایگان |

The effect of extended cycling on lithium metal electrodes has been investigated in an ionic liquid electrolyte. Cycling studies were conducted on lithium metal electrodes in a symmetrical Li|electrolyte|Li coin cell configuration for 5000 charge–discharge cycles at a current density of 0.1 mA cm− 2. The voltage–time plots show evidence of some unstable behavior which is attributed to surface reorganization. No evidence for lithium dendrite induced short circuiting was observed. SEM imaging showed morphology changes had occurred but no evidence of needle-like dendrite based growth was found after 5000 charge–discharge cycles. This study suggests that ionic liquid electrolytes can enable next generation battery technologies such as rechargeable lithium-air, in which a safe, reversible lithium electrode is a crucial component.
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► Extended lifetime study of Li anode using an ionic liquid electrolyte.
► 2500 hours of charging/discharging cycles of Li|electrolyte|Li coin cells achieved.
► Protective solid electrolyte interphase (SEI) layer prevents dendritic growth of Li.
Journal: Electrochemistry Communications - Volume 27, February 2013, Pages 69–72