کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1798069 | 1524803 | 2016 | 5 صفحه PDF | دانلود رایگان |

• Study of preparation, structural and magnetic properties of Co(Cr1−xAlx)2O4(x=0.0−1.0)Co(Cr1−xAlx)2O4(x=0.0−1.0).
• Observation of enhancement in the magnetization up to 50% of Al substitution and reduction beyond 50% Al substitution.
• Influence of the non-magnetic Al substitution on the various magnetic phase transitions in CoCr2O4 and importance of Cr-site.
• Plausible explanation for these variations in the magnetic properties of Co(Cr1−xAlx)2O4Co(Cr1−xAlx)2O4.
Here we report on the preparation, structural and magnetic properties of solid solutions of Co(Cr1−xAlx)2O4Co(Cr1−xAlx)2O4. Substituted Al ions are found to occupy the B-site of the spinel structure. Enhancement in the magnetization is noticed up to 50% of Al substitution, beyond which it decreases. Further, the decrement in ferrimagnetic ordering temperature is observed on gradually introducing the non-magnetic Al into magnetic Cr-site. All these variations in the magnetic properties of Co(Cr1−xAlx)2O4Co(Cr1−xAlx)2O4 are ascribed to the reduction of the magnetization of B-site and weakened conical spin-spirals of the CoCr2O4 with the Al substitution.
Journal: Journal of Magnetism and Magnetic Materials - Volume 418, 15 November 2016, Pages 231–235