کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
179809 | 459362 | 2012 | 4 صفحه PDF | دانلود رایگان |
Simultaneously performed in situ conductance and spectro-electrochemical measurements—completed by EQCN—proved that fast redox switching can only be expected in cation exchanger type polymers, where the conductance develops promptly with the formation of mono-cationic/polaronic charge carriers—due assumingly to the presence of the charge compensating anions in favorable distribution.
The fast redox switching in cation exchanger type polymers.Figure optionsDownload as PowerPoint slideHighlights
► Simultaneous in situ conductance and spectro-electrochemistry—completed by EQCN.
► Case A: the development of conducting state related to first charge carriers.
► Redox transformation starts always with cation removal.
► Case B: the development of conducting state is delayed, related to dications.
► Redox transformation connected always to anion movements.
Journal: Electrochemistry Communications - Volume 18, 2012, Pages 16–19