کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
179822 | 459362 | 2012 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Layered Na[Ni1/3Fe1/3Mn1/3]O2 cathodes for Na-ion battery application Layered Na[Ni1/3Fe1/3Mn1/3]O2 cathodes for Na-ion battery application](/preview/png/179822.png)
Na-ion batteries were tested with layered Na(Ni1/3Fe1/3Mn1/3)O2 cathodes and carbon anodes in a sodium-salt containing organic ester carbonate electrolyte. Layered single phase Na(Ni1/3Fe1/3Mn1/3)O2 was synthesized from solid-state reaction using a (Ni1/3Fe1/3Mn1/3)C2O4 oxalate precursor and Na2CO3 fired at 850 °C with slow-cooling. The Na-ion NayC/Na1 − y(Ni1/3Fe1/3Mn1/3)O2 cell had an average voltage of ~ 2.75 V, modest capacity of 100 mA h g− 1 for 150 cycles (1.5–4.0 V), and a capacity of 94 mA h g− 1 at a 1 °C rate. X-ray diffraction (XRD) data of extracted cycled electrodes were used to characterize material stability and phases formed upon cycling. It was found that Na1 − y(Ni1/3Fe1/3Mn1/3)O2 (0 ≤ y ≤ 0.46) maintains a layered structure with good crystallinity over 150 cycles. These results bode well for the development and optimization of rechargeable Na-ion batteries.
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► A Na-ion battery was cycled with Na[Ni1/3Fe1/3Mn1/3]O2 and carbon electrodes.
► Approximately y~0.46 Na reversibly intercalates in Na1–y[Ni1/3Fe1/3Mn1/3]O2.
► Over 150 cycles at a 0.5C rate with NayC/Na1–y[Ni1/3Fe1/3Mn1/3]O2 cell was shown.
► 1C rate (current density of 150 mA g–1) yielded a high capacity of 94 mA h g–1.
Journal: Electrochemistry Communications - Volume 18, 2012, Pages 66–69