Grouping trends of magnetic permeability components in their parallel evolution with microstructure in Ni0.3Zn0.7Fe2O4

• A similar trend between multi-sample sintering and single-sample sintering.
• Difference in the values due to difference in surface reactivity.
• Single-sample-sintering: absence of statistical error besides being cost effective.
• Selectivity of appropriate sintering temperature for specific applications.

Ni–Zn ferrite, Ni0.3Zn0.7Fe2O4, with a wide variation of grain sizes has been prepared via high energy ball milling through two different sintering routes: multi-sample sintering and single-sample sintering. The parallel relationships between evolving microstructural properties and AC magnetic response parameters were investigated using a FEI Nova NanoSEM 50 series and an Agilent Model HP4291B Impedance/Material Analyzer respectively. SEM micrographs showed larger grain size as the sintering temperature increased, consequently increasing the number of multi-domain grains. The AC magnetic response parameters belong to three groups with strongly, moderately and weakly ferromagnetic behavior respectively. Single-sample sintering and multi-sample sintering evolution yield quite similar permeability-grain size relationship trends. The permeability from both sintering routes is influenced by several factors which are degree of crystallinity, dominant magnetization process (ease of domain walls movement in multi-domain grains or spin rotation in single-domain grains) and large enough grain size which surpasses the critical grain size for transition from single-domain to multi-domain grains.