Magnetocaloric properties and exchange bias effect in Al for Sn substituted Ni48Mn39.5Sn12.5 Heusler alloy ribbons

• Ni48Mn39.5Sn12.5−xAlx (x=0, 1, 2, 3) melt spun ribbons are found to show exchange bias (EB) effect.
• The Al for Sn substitution appears to enhance EB.
• Around As the magnetic field induces the RMT giving rise to the inverse MCE.
•  The highest ΔSM at H= 2 T is observed for the Ni48Mn39.5Sn12.5 ribbon.

The influence of Al substitution for Sn on magnetocaloric properties and exchange bias behavior in Ni48Mn39.5Sn12.5−xAlx (x=0, 1, 2, 3) melt spun ribbons have been investigated. All the studied ribbons undergo a martensitic and reverse transformation. At low temperature martensite region, below 100 K, the alloys exhibit exchange bias effect, which appears to enhance with the increase of Al concentration. The loop shift difference (ΔHE) of up to 7960 A m−1 is recorded between the ribbon containing no Al and the ribbon with x=3. The presence of exchange bias behavior in these samples is attributed to the coexistence of antiferromagnetic and ferromagnetic exchange interactions. The magnetic entropy change and refrigerant capacity are evaluated for the ribbons studied around both the structural and magnetic transformations under the applied magnetic field induction of 2 T. The maximum entropy change around the magnetic transition and around the structural transition is reported for the Ni48Mn39.5Sn12.5 ribbon, and the entropy values amount to 1.8 and 7.8 J kg−1 K−1, respectively.