Magnetoelectric properties of particulate and bi-layer PMN-PT/CoFe2O4 composites

Our studies comprise electrical dielectric and magnetoelectric properties of CoFe2O4 (CFO) and Pb(Mg1/3Nb2/3)0.67Ti0.33O3 [PMN-PT] magnetoelectric composites. The individual phases were prepared by conventional ceramic method. The particulate composites of ferrite and ferroelectric phases were prepared in ferroelectric rich region. Presence of both the phases in the composites was confirmed using X-ray diffraction techniques. The scanning electron microscopic images recorded in backscattered mode were used to study the microstructure of composites. Lattice constant, dielectric constant, electrical resistivity, ferroelectric, and magnetic properties of individual as well as particulate composites were studied. Further the bi-layer composites were made using the discs obtained from the powders of individual phases where hot press technique was employed to obtain disc of individual phases. CFO phase used in bi-layer composites was obtained using chemical co-precipitation technique. Magnetoelectric (ME) measurements were carried out on both, particulate and layered magnetoelectric composites. Comparison of ME signal obtained from particulate and layered composites revealed that the layered composites gives superior magnetoelectric signal. ME data obtained for layered composites show good agreement with the theoretical model.

▸ Study on dielectric, electrical, ferroelectric, and magnetic properties of particulate magnetoelectric composite of PMN-PT/CFO. ▸ These properties are correlated with the magnetoelectric effect in particulate composites. ▸ Magnetoelectric properties of particulate composites are compared with bilayer magnetoelectric composites of PMN-PT/CFO. ▸ Magnetoelectric signal obtain for bilayer composites show good agreement with theoretical model suggested by Bichurin et al.