کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
180046 | 459369 | 2012 | 4 صفحه PDF | دانلود رایگان |

Hierarchical mesoporous γ-MnO2 nanospheres with high crystallinity were prepared by a template-free self-assembly under applied ultrasonic waves, resulting in a solid spherical nanostructure with stacking of nanosized worm-like particles. This approach based on ultrasound exposure reduces the particle size and enhances the crystallinity of γ-MnO2, leading to a large effective area for the active domains and a stable structural arrangement of the active materials. The applicability of γ-MnO2 to high-power lithium batteries is demonstrated, based on improved capacity, excellent rate capability, and stable cyclability, which stem from the outstanding physical properties of the hierarchical mesoporous nanostructure.
► 3D hierarchically mesoporous γ-MnO2 nanospheres.
► Facile synthetic method using ultrasonic waves.
► Ultrasonic waves increase single-crystalline active domain size and enhance mechanical integrity.
► Mesoporous nanostructures with high crystallinity can improve electrochemical performance.
Journal: Electrochemistry Communications - Volume 14, Issue 1, January 2012, Pages 32–35