کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
180136 | 459371 | 2011 | 5 صفحه PDF | دانلود رایگان |
In situ atomic force microscopy (AFM) and spectroscopic ellipsometry were used to study the mechanism of organic carbonate electrolytes decomposition and surface layer (re)formation at β-Sn(001) and (100) single crystal electrodes. Interfacial phenomena were investigated at potentials above 0.8 V vs. Li/Li+, i.e. where no Sn–Li alloying takes place. The Sn(001) electrode tends to form a protective surface layer of electrolyte reduction products during the first cathodic CV scan, which effectively inhibits further reduction of the electrolyte upon cycling. In contrast, the Sn(100) electrode produces a thick, inhomogeneous and unstable surface layer. The observed significant difference of Sn reactivity toward the electrolyte as a function of Sn surface crystalline orientation suggests radically different reaction paths, reduction products, and properties of the surface film.
► Sn reactivity in organic electrolytes varies with surface crystalline orientation.
► Sn(100) single crystal electrode does not form an effective passivation layer.
► Sn(001) single crystal electrode develops a thin homogeneous passivation layer.
► Different reaction paths and electrolyte reduction products on Sn crystal facets.
► Sn interfacial stability can be achieved through optimizing the surface structure.
Journal: Electrochemistry Communications - Volume 13, Issue 11, November 2011, Pages 1271–1275