کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1801590 1024572 2008 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
An Ising ferrimagnet with layered and chained magnetic sublattices: Ca2FeMnO5Ca2FeMnO5
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
An Ising ferrimagnet with layered and chained magnetic sublattices: Ca2FeMnO5Ca2FeMnO5
چکیده انگلیسی

Nakahara et al. [Mater. Lett. 30 (1997) 163–167] have refined their X-ray diffraction patterns of Ca2FeMnO5Ca2FeMnO5 with the brownmillerite structure, in which all the octahedral in-plane sites are occupied by Mn, and all the tetrahedral in-chain sites are occupied by Fe. Our Mössbauer study of Ca2FeMnO5Ca2FeMnO5 is in agreement with this cationic distribution. We determine the spin orientation with respect to the crystal axes and suggest the model of layered magnetic structure. From our Mössbauer spectra and from analysis of the crystal and magnetic structures in a number of brownmillerite-related oxides we suggest for Ca2FeMnO5Ca2FeMnO5 the mixed-spin S=52 and S=2S=2 Ising system. The Fe3+Fe3+ and Mn3+Mn3+ moments order antiferromagnetically (AFM) both in-plane and in perpendicular direction and aligned up and down vertically in the out-of-plane direction. Although we cannot exclude a small tilt and a related small ferromagnetic component, basically, each of Fe and Mn spin subsystems generate individually a C-type sublattice and two these sublattices are superposed to give an unusual G-like type structure with two sorts of spins. Nuclear forward scattering (NFS) and nuclear inelasting scattering (NIS) techniques were used to characterize, respectively, the hyperfine interactions and phonon density of states (DOS) of 57Fe. Comparing the vibrational properties of several brownmillerites we were able to give an approximate DOS for tetrahedral and octahedral positions.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetism and Magnetic Materials - Volume 320, Issue 6, March 2008, Pages 950–956
نویسندگان
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