Magnetism in ordered metallic perovskite compound GdPd3BxC1-xGdPd3BxC1-x

We report results of dc-magnetization, ac-susceptibility and magnetoresistance measurements on crystalline metallic-perovskite compounds GdPd3BxC1-xGdPd3BxC1-x (x=0.25x=0.25, 0.50, 0.75 and 1.00) and the parent cubic compound GdPd3GdPd3. The interest in these materials stems from the observation of negative temperature coefficient of resistance and negative thermal expansion in some of the members of this series. In the present study, we show that by substitution of non-magnetic elements, boron and carbon, the nature of the magnetic interaction can be varied from dominating ferromagnetic to antiferromagnetic and finally to a canted magnetic structure without altering the crystal symmetry of the compounds. The variation of magnetic interaction by modifying the lattice parameter resembles Ruderman–Kittel–Kasuya–Yosida (RKKY) oscillations.