کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1803812 1524903 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Direct detection of optically-induced microwave spin precession in Fe(III) halogenates
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
Direct detection of optically-induced microwave spin precession in Fe(III) halogenates
چکیده انگلیسی

Picosecond optical excitation of electron spin precession has been observed at room temperature by detecting an induced EMF for acetone solutions of tetraethylammonium iron(III) tetrachloride ((C2H5)4NFeCl4), tetraethylammonium iron(III) tetrabromide ((C2H5)4NFeBr4), and iron(III) trichloride (FeCl3). A detection bandwidth of 7 GHz allowed the free induction decay (FID) signal with a sub-nanosecond decay time. Magnetic field dependence of the FID frequency for (C2H5)4NFeCl4 is well fitted with the Zeeman energy splitting given by the S  =52 spin Hamiltonian with a g-value of 2.015±0.007 and a zero fine structure constant. A Fourier transform of the FID waveform shows a Lorentzian shape. The dephasing time T2 coincides with the longitudinal decay time T1 and is independent of the magnetic field, indicating that the spin system we studied is under the motional narrowing regime. The optical technique allows Fourier transformed (FT) ESR without microwave excitation at an arbitrary magnetic field.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetism and Magnetic Materials - Volume 317, Issues 1–2, October 2007, Pages 8–14
نویسندگان
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