کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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180418 | 459380 | 2010 | 4 صفحه PDF | دانلود رایگان |

In this paper, we discuss the synthesis and electrochemical properties of a new material based on iron oxide nanoparticles stabilized with poly(diallyldimethylammonium chloride) (PDAC); this material can be used as a biomimetic cathode material for the reduction of H2O2 in biofuel cells. A metastable phase of iron oxide and iron hydroxide nanoparticles (PDAC–FeOOH/Fe2O3-NPs) was synthesized through a single procedure. On the basis of the Stokes–Einstein equation, colloidal particles (diameter: 20 nm) diffused at a considerably slow rate (D = 0.9 × 10− 11 m s− 1) as compared to conventional molecular redox systems. The quasi-reversible electrochemical process was attributed to the oxidation and reduction of Fe3+/Fe2+ from PDAC–FeOOH/Fe2O3-NPs; in a manner similar to redox enzymes, it acted as a pseudo-prosthetic group. Further, PDAC–FeOOH/Fe2O3-NPs was observed to have high electrocatalytic activity for H2O2 reduction along with a significant overpotential shift, ΔE = 0.68 V from − 0.29 to 0.39 V, in the presence and absence of PDAC–FeOOH/Fe2O3-NPs. The abovementioned iron oxide nanoparticles are very promising as candidates for further research on biomimetic biofuel cells, suggesting two applications: the preparation of modified electrodes for direct use as cathodes and use as a supporting electrolyte together with H2O2.
Journal: Electrochemistry Communications - Volume 12, Issue 11, November 2010, Pages 1509–1512