کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
180671 | 459386 | 2009 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Spectroelectrochemistry for studying electrochemiluminescence mechanism
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
UV–Vis spectroelectrochemistry (SEC) was introduced for the first time into the study of electrochemiluminescence (ECL) mechanisms of nitrogen heterocyclic compounds. Uracil and its two derivatives, 5-fluorouracil and 1-methyl-uracil, were chosen as model molecules in the ECL mechanism study. SEC revealed that the substitution of hydrogen at N(1) and the destruction of conjugate heterocyclic ring were very important for ECL activities of uracils. On the basis, a new ECL mechanism was proposed for the uracils. The successful explanation of ECL mechanism for the model molecules by employing SEC indicates that SEC would play an important role in future ECL mechanism studies.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 11, Issue 5, May 2009, Pages 983–986
Journal: Electrochemistry Communications - Volume 11, Issue 5, May 2009, Pages 983–986
نویسندگان
Yongqiang Dong, Yuwu Chi, Liyan zheng, Lan Zhang, Lichan Chen, Guonan Chen,