کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
180784 | 459389 | 2010 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical reduction of aliphatic conjugated dienes in the presence of carbon dioxide
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
A voltammetric and electrolytic study involved in the electroreductive carboxylation of multi-substituted aliphatic coujugated dienes has been successfully conducted. With methyl sorbate as the modal compound, acceptable yields of carboxylation and dimerization were achieved, which were influenced by various reaction conditions such as the supporting electrolyte, cathode nature, current density, charge passed and temperature. A correlation was first established between distinct electronic effects of the dienes and the electrochemical characteristics of their reduction and the distribution law of target products.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 12, Issue 12, December 2010, Pages 1698–1702
Journal: Electrochemistry Communications - Volume 12, Issue 12, December 2010, Pages 1698–1702
نویسندگان
Kai Zhang, Yuanjing Xiao, Yangchun Lan, Meixia Zhu, Huan Wang, Jiaxing Lu,