کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
180917 | 459392 | 2010 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical characters and structure changes of electrochemically treated Pt nanoparticles
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Electrochemical characters and structure changes of electrochemically treated Pt nanoparticles Electrochemical characters and structure changes of electrochemically treated Pt nanoparticles](/preview/png/180917.png)
چکیده انگلیسی
In this paper, the surface and electrochemical characters of the Pt/CNT electrode before and after voltammetric cyclings were studied using high resolution transmission electron microscopy imaging (HRTEM), X-ray photon electron spectroscopy (XPS) and cyclic voltammetry measurements of CO and methanol oxidation. It was found that Pt nanoparticles were not stable and formed the linked and agglomerated structures. The changes of the crystallites led to the peak multiplicity, the negative shift of CO oxidation peaks, and the increase of the current density of methanol oxidation. We considered the specific activities were due to the increases of oxygen species and defect sites on Pt.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 12, Issue 1, January 2010, Pages 14–17
Journal: Electrochemistry Communications - Volume 12, Issue 1, January 2010, Pages 14–17
نویسندگان
Huiping Yuan, Huanqiao Song, Xinping Qiu, Wentao Zhu, Liquan Chen,