کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
181279 | 459399 | 2009 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Non-aqueous vanadium acetylacetonate electrolyte for redox flow batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
The electrochemistry of a single-component redox flow battery employing vanadium(III) acetylacetonate in acetonitrile and tetraethylammonium tetrafluoroborate has been investigated. The electrode kinetics of the anodic and cathodic reactions were studied using cyclic voltammetry. The V(II)/V(III) and V(III)/V(IV) couples were quasi-reversible and together yielded a cell potential of 2.2 V. The diffusion coefficient for vanadium acetylacetonate was estimated to be in the range of 1.8–2.9 × 10−6 cm2 s−1 at room temperature. The charge–discharge characteristics of this system were evaluated in an H-type glass cell, and coulombic efficiencies near 50% were achieved.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 11, Issue 12, December 2009, Pages 2312–2315
Journal: Electrochemistry Communications - Volume 11, Issue 12, December 2009, Pages 2312–2315
نویسندگان
Qinghua Liu, Alice E.S. Sleightholme, Aaron A. Shinkle, Yongdan Li, Levi T. Thompson,