کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
181396 | 459401 | 2009 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Physical and electrochemical characterizations of nanostructured Pd/C and PdNi/C catalysts for methanol oxidation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Pd and PdNi nanoparticles supported on Vulcan XC-72 carbon were prepared by a chemical reduction with formic acid process. The catalysts were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), cyclic voltammetry, and chronoamperometry. The results showed that the Pd and PdNi nanoparticles, which were uniformly dispersed on carbon, were 2–10 nm in diameters. The PdNi/C catalyst has higher electrocatalytic activity for methanol oxidation in alkaline media than a comparative Pd/C catalyst and shows great potential as less expensive electrocatalyst for methanol electrooxidation in alkaline media in direct methanol fuel cells.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 11, Issue 4, April 2009, Pages 925–928
Journal: Electrochemistry Communications - Volume 11, Issue 4, April 2009, Pages 925–928
نویسندگان
Zhaolin Liu, Xinhui Zhang, Liang Hong,