کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
182158 | 459419 | 2008 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Asymmetry between charge and discharge during high rate cycling in LiFePO4 – In Situ X-ray diffraction study
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Asymmetry between charge and discharge during high rate cycling in LiFePO4 – In Situ X-ray diffraction study Asymmetry between charge and discharge during high rate cycling in LiFePO4 – In Situ X-ray diffraction study](/preview/png/182158.png)
چکیده انگلیسی
Asymmetric behavior of structural changes during charge and discharge of C-coated LiFePO4 has been investigated using synchrotron based in situ XRD. C-coated LiFePO4 undergoes phase transformation from triphylite to heterosite during charge and vise versa during discharge. However, it is observed that the phase transformation of C-coated Li1−xFePO4 during discharge is more difficult to be complete than that during charge. At 2C rate, the phase transformation from heterosite to triphylite was hardly observed during discharge while the complete phase transformation was observed in the previous charge. This indicates that the degree of the phase transformation completeness depends on the direction of the phase transformations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 10, Issue 4, April 2008, Pages 536–540
Journal: Electrochemistry Communications - Volume 10, Issue 4, April 2008, Pages 536–540
نویسندگان
Ho Chul Shin, Kyung Yoon Chung, Won Sik Min, Dong Jin Byun, Ho Jang, Byung Won Cho,