کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
182445 | 459427 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
One redox probe (dmfc) can drive the transfer of anions and cations across the aqueous electrolyte∣ionic liquid interface
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: One redox probe (dmfc) can drive the transfer of anions and cations across the aqueous electrolyte∣ionic liquid interface One redox probe (dmfc) can drive the transfer of anions and cations across the aqueous electrolyte∣ionic liquid interface](/preview/png/182445.png)
چکیده انگلیسی
Three-phase electrodes consisting of droplets of 1-hexyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate containing decamethylferrocenium (dmfc+) cations, immobilized on the surface of graphite electrodes and immersed in aqueous electrolyte solutions have been employed to study the redox driven transfer of anions and cations. Very surprisingly, it has been observed that anions as well as cations can be transferred with one redox probe (dmfc/dmfc+) because the Gibbs energies of ion transfer of the different ions are rather similar.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 8, Issue 6, June 2006, Pages 967–972
Journal: Electrochemistry Communications - Volume 8, Issue 6, June 2006, Pages 967–972
نویسندگان
Victor Agmo Hernández, Fritz Scholz,