کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
182470 | 459429 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical study of hydrophilic ion transfers across cholesterol modified water–nitrobenzene interface by means of thin film electrodes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Electrochemically driven ion transfer reactions of ClO4-, NO3-, SCN−, and K+ across a cholesterol modified water–nitrobenzene (W–NB) interface have been studied by means of square-wave and cyclic voltammetry at thin organic film modified electrodes. It has been found that cholesterol exhibits a profound accelerating effect toward the kinetics of ClO4-, NO3-, SCN− transfers, whereas a retarding kinetic effect was observed for K+. Besides, the cholesterol layer alters significantly the mechanism of ion transfer, prompting adsorption of all studied ions as a consequence of specific interactions between cholesterol molecules and the transferring ion.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 9, Issue 10, October 2007, Pages 2489–2495
Journal: Electrochemistry Communications - Volume 9, Issue 10, October 2007, Pages 2489–2495
نویسندگان
François Quentel, Valentin Mirčeski, Maurice L’Her, Filip Spasovski, Marta Gaćina,