کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
182677 459436 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Study of the electropolymerization of tetrakis (3-aminophenyl) porphyrin Fe(III) chloride on Au electrodes by cyclic voltammetry and STM
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Study of the electropolymerization of tetrakis (3-aminophenyl) porphyrin Fe(III) chloride on Au electrodes by cyclic voltammetry and STM
چکیده انگلیسی

Conducting tetrakis (3-aminophenyl) porphyrin Fe(III) chloride films are prepared by electropolymerization on Au(1 1 1) electrodes in DMF + TBAP solutions by cycling the potential between −1.6 and 1.5 V vs. SCE at 0.2 V s−1. The film thickness is controlled through the number of cycles and the voltammetric response of the modified electrode is stable and reproducible. STM images show that during the first 20 cycles only 2D islands 0.35 nm high and up to 50 nm long are formed. These islands grow laterally by the incorporation of new oligomers on their borders. When the electrode surface is almost fully covered a transition from 2D to 3D growth is observed. This transition in the growth mode can be followed through the anodic charge of the cyclic voltammograms.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 8, Issue 5, May 2006, Pages 779–784
نویسندگان
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