کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
182749 459440 2006 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A new method for the preparation of PtPd alloy single crystal surfaces
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
A new method for the preparation of PtPd alloy single crystal surfaces
چکیده انگلیسی

A new method for the preparation of PtPd single crystal alloy surfaces is described. Using the ‘forced deposition’ method followed by gentle flame annealing, it is demonstrated that well-defined epitaxial PtPd surface alloy films supported on Pt single crystal electrodes may be synthesised covering the whole range of surface alloy composition. The surfaces prepared by this method have been characterised by cyclic voltammetry (CV) in H2SO4 and also via copper underpotential deposition (Cu UPD). The most interesting facet of this new method is the ease of preparation of PtPd{h k l} alloy surfaces relative to analogues derived from bulk PtPd single crystals, although in this paper, only the characterisation of PtPd{1 1 0} is presented.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 8, Issue 7, July 2006, Pages 1147–1150
نویسندگان
, , , ,