Self-modulation of infrared waves in rutile

Electromagnetic waves carry angular and linear momentums and exert torques on anisotropic dielectrics, arising from the fact of the tensor property of the dielectric constant, that is, the direction of electric displacement is not parallel to the electric field vector of the incident light. The torque per unit volume exerted on a wave plate is given by P×E, where P is the polarization and E is the electric field, which induces the rotations of eigenvibration direction in the crystals. The rotation angles increase with the intensity of the incident light and the dielectric constant of the crystals. Because of the large dielectric constants, self-modulation of the incident light in the infrared frequency region was clearly demonstrated in the infrared transmission spectra of ferroelectric and piezoelectric crystals. Rutile (TiO2) is a non-ferroelectric and non-piezoelectric crystal, but it also has the large dielectric constants. Rotations of the vibration direction of the ordinary (o-ray) and the extraordinary (e-ray) waves were shown in the infrared transmission spectra recorded by incidence of the plane-polarized light and transmission through a rutile plate. Interference of the o-ray and the e-ray waves transmitted through the crystals confirms the rotations of eigenvibration direction, a self-modulation effect of light in the crystal of large dielectric constants and large birefringence in the infrared range.