Gigantic stimulated Raman scattering in one-dimensional Mott-Hubbard insulators: A possible THz source

One-dimensional Mott-Hubbard insulators like Sr2CuO3, halogen-bridged Nickel chain compounds have orders-of-magnitude nonlinear optical properties compared to other one-dimensional organic or inorganic compounds. We show theoretically, that the stimulated Raman scattering susceptibility for such insulators could be order(s)-of-magnitude larger even compared to other nonlinear optical susceptibilities. The lowest two-photon state is at lower energy than the lowest one-photon state in some of these insulators. This leads to a potential for strong Stokes generation in the THz regime from these compounds. Our results and conclusions are based on exact numerical solution of finite size two-band extended Hubbard model.