Phase field modeling of Widmanstatten plate formation in Zr–2.5Nb material

Growth of Widmanstatten side-plates from pre-nucleated α in a matrix of β is a diffusion controlled process. The phase-field approach is formulated for Widmanstatten side plate formation through β-Zr (B.C.C) → α-Zr (HCP) transformation in binary substitutional Zr–2.5Nb alloy. Using Gibbs energy functional and diffusional mobility, microstructural evolution of parallel side-plates from pre-nucleated α phase has been simulated. The highly anisotropic nature of Widmanstatten plate and the presence of thin interface at the parent-product interface make the task challenging for FEM analysis. Based on this model, an estimate on the range of temperature over which Widmanstatten parallel side-plates can form is estimated and the extent of anisotropy of surface free energy on the morphology of the plates is analyzed.