Synergistic effect of various neutral donors in D2EHPA for selective neodymium separation from lanthanide series via HFSLM

• The separation of Nd(III) from lanthanide series via HFSLM using synergistic extractant was investigated.
• Optimum extraction and stripping were 94.5% and 85.1% using D2EHPA and TOPO mixtures as the synergistic extractant.
• Both extraction and stripping was first-order reaction with rate constants of 1.444 and 1.338 min−1.
• The experimental results were used to correlate with the models.
• The average deviation was 1.95% and 2.18% for predictions in feed and stripping sides.

The separation of Nd(III) from lanthanide series via hollow fiber supported liquid membrane (HFSLM) using synergistic extractant was investigated. Optimum extraction and stripping obtained were 94.5% and 85.1% using D2EHPA and TOPO mixtures (0.5:0.5 M/M) as the synergistic extractant. Reaction order for both extraction and stripping were first-order with rate constants of 1.444 and 1.338 min−1, respectively. The experimental results were used to correlate with the models. Results showed that the concentration of Nd(III) from the experiment fitted in well with the model results. The average deviation was 1.95% and 2.18% for predictions in both feed and stripping sides, respectively.

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