کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
227699 464826 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Commercially attractive process for production of 5-hydroxymethyl-2-furfural from high fructose corn syrup
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Commercially attractive process for production of 5-hydroxymethyl-2-furfural from high fructose corn syrup
چکیده انگلیسی

5-Hydroxymethyl-2-furfural (HMF) was prepared with high fructose corn syrup (HFCS) manufactured directly from industry. Equipped industrial process and cheaper availability considered HFCS-90 as a competitive starter for production of HMF. Readily evaporable solvent, 1,4-dioxane was found as a promising reaction media from the screening of various solvents and readily available cation exchange resin, Amberlyst-15 was used as a solid acid catalyst. Parametric variation studies including amount of catalyst, concentration of HFCS-90, and reaction temperature were performed to achieve a maximum HMF yield of 80% at 100 °C within 3 h. In particular, use of readily evaporable solvent and heterogeneous catalyst allowed highly practical purification of HMF, which still remains as a major obstacle to the commercialization of HMF. With filtration, evaporation, and extraction, HMF was simply isolated in 72% yield and 1H NMR spectra of the isolated HMF confirmed that its purity was sufficient for use in next step of reactions. In addition, all solvents could be recycled with distillation and catalyst was reused up to 5 cycles without a significant loss of activity.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Industrial and Engineering Chemistry - Volume 19, Issue 4, 25 July 2013, Pages 1106–1111
نویسندگان
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