کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
227704 | 464826 | 2013 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Ring-opening polymerization behavior of l-lactide catalyzed by aluminum alkyl catalysts
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
The l-lactide polymerization using trimethylaluminum (TMA), triethylaluminum (TEAL), trioctylaluminum (TOA), triisobutylaluminum (TIBA), and aluminum isopropoxide (Al(O-i-Pr)3) were studied to produce a PLA. The conversion, turnover frequency (TOF), and molecular weight of TIBA were higher than those of Al(O-i-Pr)3 with the polymerization time of 5 min. In the case of 15 min, the conversion of aluminum alkyls was lower than that of Al(O-i-Pr)3, but the molecular weight of PLA produced by aluminum alkyl was relatively high in comparison with the catalytic activity of Al(O-i-Pr)3. TMA, TEAL, and TIBA seemed to have lower propagation rates and much lower termination rates than Al(O-i-Pr)3.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Industrial and Engineering Chemistry - Volume 19, Issue 4, 25 July 2013, Pages 1137–1143
Journal: Journal of Industrial and Engineering Chemistry - Volume 19, Issue 4, 25 July 2013, Pages 1137–1143
نویسندگان
Ji Yun Yoo, Youngjo Kim, Young Soo Ko,